rsingh wrote:
It explains very well. Thanks
I am glad it was helpful ..
All - few comments..
SriKumar wrote:A follow-up question.....if there is a layer of water over a flat surface, e.g. say someone pours a cup of water on stone surface; Assume air, water and the stone surface are all at the same temperature (30 C, say). Would we expect the water to evaporate?...
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Yes, as you said, the stone surface will become cooler.
Also, on a stone, after the water is gone (stone is dry) the process will stop.
On a Matka (clay pot), since it is porous, more water will come to the outer surface, which will keep out side wet for the water to evaporate and the water will get cooler for a longer time. In fact, since the out side
surface of a matka is more than, say the top part of an open container, it is better water cooler.
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Yes the water will
get cooler than its surroundings.
.. If the answer is yes, it seems to suggest that heat flowed from a cooler surface to warmer surface...
Well unlike the first law of thermodynamics, which says energy is conserved, the second law of thermodynamics only says that it is **less likely ** for heat to flow from "cooler" to "warmer".. NOT IMPOSSIBLE.
In other words, some times, (or on molecular level ), a high energy molecule can move from "colder" (where other molecules are slower and thus on "average" - temp is lower, to a "warmer" place...
So on "local level (or open systems) you may see such things.. but not at larger level.
In a strict sense, if you are holding a glass of water, and you wait LONG enough (say trillion times the age of universe

) ..it may happen that top part of water may boil while bottom left corner forms ice
Except that it is NOT likely to happen. (Probability is pretty close to zero).
If you are not familiar with term like "Maxwell Demon" (See wiki entry or Gamow's excellent "Mr Tomkins book") The ebook link ;
http://ebooks.cambridge.org/chapter.jsf ... 644143A018
BTW, if you have not seen/read it, as I have done many times before, I HIGHLY recommend George Gamow's book(s) - "Mr Tomkins in Paperback"
(It explains, Relativity, Space/Time, Thermodynamics, nuclear Physics etc in simple terms)
some quotes from previous posts, relevant to this.
Following are some relevant observations: (i) if one sprinkles water on a surface and it evaporates, the area feels cooler after some time. (ii) Water stored in a desi matka (earthen pot) is definitely cooler than water in a glass/cup, and this, as I understand, is due to the evaporation of water from the matka surface....(so some capillary effect is also at work here).
LokeshC wrote:.... and how can heat flow from a "cooler object" to a hotter object (2nd law of thermodynamics)?
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Humidity is related to how much water vapor is already in the air - more humid the air-- less evaporation. At 100% (R) humidity there is no evaporation - that is the number of water molecules leaving the surface of water is (on average) equal to number of water molecules from air entering the water and getting stuck inside.
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